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Thermal Cracking. Thermal cracking is a free radical chain reaction which determines the product distribution during thermal cracking—a significant feature of such reactions is the resistance of hydrocarbon free radicals to isomerization. From: Fouling in Refineries, 2015. Related terms: Crude Oil; Pyrolysis; Hydrogen; Viscosity; Distillation; Feedstocks Hydrocracking is an important source of diesel and jet fuel. Source: Millennium Global, Inc., used with permission. A hydrocracking unit, or hydrocracker, takes gas oil, which is heavier and has a higher boiling range than distillate fuel oil, and cracks the heavy molecules into distillate and gasoline in the presence of hydrogen and a catalyst.